The intensities of the AM = \*1 component of the 'Fe -c ' D2 transition in D3 complcves containmg the [ Eu09 1 ctustcr, and of other d-d or f-f tiansltlons in D3 complexes with the yz-and xz-components of the electric quadrupole as the Ieading moment, are found to be dependent upon the pohrlzablty a
The ligand polarization model for transition probabilities in the electronic spectra of metal complexes
β Scribed by Stephen F. Mason
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 260 KB
- Volume
- 60
- Category
- Article
- ISSN
- 0022-2860
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Expressions are given for the calculation of activation energies for ligand substitution in transition metal complexes. A comparison between calculated and experimental activation energies for the substitution of water molecules shows reasonably good agreement.