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Vibrational-electronic interaction in the infrared circular dichroism spectra of transition-metal complexes

✍ Scribed by C.J. Barnett; A.F. Drake; R. Kuroda; S.F. Mason; S. Savage

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
222 KB
Volume
70
Category
Article
ISSN
0009-2614

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✦ Synopsis

The cuculor dichrolsm spectra of the quasi-tetrahedral complexes pf translhon-metal Ions with (-)-spartem, IM(Z-sp)Clz], over the C-H stretchmg vlbratlon range, show nn optrcal actlmty wh I 1s weak in the Zn(Il) case. but enhanced m the Co(H) and NM) analogues through the coupling of the sharp vibrational trdnsitlon with underlying broad d-d electronic excltauon

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