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Anisotropic contributions in the ligand polarization model for the f-f transition probabilities of Eu(III) complexes

✍ Scribed by Reiko Kuroda; Stephen F. Mason; Carlo Rosini

Publisher: Elsevier Science
Year: 1980
Tongue: English
Weight: 470 KB
Volume: 70
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(80)80050-9

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✦ Synopsis

The intensities of the AM = *1 component of the 'Fe -c ' D2 transition in D3 complcves containmg the [ Eu09 1 ctustcr, and of other d-d or f-f tiansltlons in D3 complexes with the yz-and xz-components of the electric quadrupole as the Ieading moment, are found to be dependent upon the pohrlzablty amsotropy of the wds. 'Lhe expectation is supported by determinations of the smgle-cwstal absorption mtensities of Nas [Eu(diglycoUate)3] -2NaC104 .6Hz0 and [Eu(H~O)~] K2-W04)3.

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