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The Lewis basicity of the [Pt3(μ-CO)3(PR3)3] clusters and the X-ray crystal structure of [{ZnI2}{Pt3(μ-CO)3(PPh(i-Pr)2)3}]

✍ Scribed by Andreas Stockhammer; Klaus-Hermann Dahmen; Tobias Gerfin; Luigi M. Venanzi; Volker Gramlich; Walter Fetter

Publisher
John Wiley and Sons
Year
1991
Tongue
German
Weight
225 KB
Volume
74
Category
Article
ISSN
0018-019X

No coin nor oath required. For personal study only.

✦ Synopsis

Dedicated to Prof. Huns-Georg uon Schnering on the occasion of his 60th birthday

(1 7.V. 9 I)

The cluster compounds [Pt,(,u-CO),(PR,),] act as Lewis bases towards the metal halides of Group XI, MX, Group XII, MX,, and Group XIII, MX,, to form cluster compounds of the composition [{MX,}{Pt3(,u-C0)3(PR3)3}]. The X-ray crystal structure, NMR and IR data are given for the compound [{ZnI} {pt,gc-Co),(pph(i-Pr)2)3}1.

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