Skeletal Isomerization of the [Pt3(μ-PPh2)3Ph(PPh3)2] Cluster by Recrystallization in Various Solvents

✍ Scribed by Dr. Robert Bender; Dr. Pierre Braunstein; Prof. Antonio Tiripicchio; Prof. Marisa Tiripicchio Camellini

• Publisher: John Wiley and Sons
• Year: 1985
• Tongue: English
• Weight: 245 KB
• Volume: 24
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.198508611

✦ Synopsis

J Y v " d Fig. I . Crystal structure of the metallacycle 2 (without hydrogen atoms). Selected bond distances [pm] and bond angles ["I: Re-01 168(1), Re-02 184(1), Re-03 202( I), C2. . .Re 289.4, 02-C2 147(2), CI . . .Re 289.9, 03-C1 133(2), 04-C1 120(2), C2-C3 155(2), C2-C9 151(2); CI-C2 151(2); 02-Re-03 79.7(4), 02-C2-CI l07(1), C3-C2-C9 110(1), CI-C2-C3 107(1), C2-CI-03 113(1), C2-02-Re l22(1), CI-03-Re IIX(l).-P2,/a; a=878.2(3), b= 1383.1( ), c = 1824.7(9) pm; / l = 101.12(4)"; V=2175.