Agostic-type Gold Ligand and Incipient μ3-PPh2 Coordination in the Au2Pt2P6 “Hammock” Skeleton of the Cluster [Au2Pt2(μ-PPh2)2(PPh3)4][PF6]2
✍ Scribed by Dr. Robert Bender; Dr. Pierre Braunstein; Dr. Alain Dedieu; Prof. Yves Dusausoy
- Publisher
- John Wiley and Sons
- Year
- 1989
- Tongue
- English
- Weight
- 341 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
J Y v " d Fig. I . Crystal structure of the metallacycle 2 (without hydrogen atoms). Selected bond distances [pm] and bond angles ["I: Re-01 168(1), Re-02 184(1), Re-03 202( I), C2. . .Re 289.4, 02-C2 147(2), CI . . .Re 289.9, 03-C1 133(2), 04-C1 120(2), C2-C3 155(2), C2-C9 151(2); CI-C2 151(2); 02-
homo)cubane or as an oxygen analogue of [4]peristylane." ' 1 Furthermore, this result corroborates the constitutional assignment, based solely on the 'H NMR and IR spectra, of a product obtained after ozonolysis of the syn dimer of tetramethylcyclobutadiene." ## Experimental Procedure Dimethylsil