The kinetics of the photochemical hydrogen abstraction in crystals of fluorene doped with acridine
โ Scribed by J.P. Colpa; D. Stehlik
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 874 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0301-0104
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๐ SIMILAR VOLUMES
Pressure dependence of the tunneling rate for the hydrogen transfer photoreaction in acridine: fluorene was investigated at 1.4 K. Above 10 kbar, the rate rises exponentially with increasing pressure. These data constitute a measurement of tunneling rate from the vibrational ground state. Its physic
The reaction rate has been measured in the temperature range 50 < 7'~ 300 K for photochemical H-abstraction by phenazine in its excited triplet state doped in fluorene single crystals. Typical features for a tunneling process like the approach to a constant low-temperature rate, a non-Arrhenius temp