The reaction rate has been measured in the temperature range 50 < 7'~ 300 K for photochemical H-abstraction by phenazine in its excited triplet state doped in fluorene single crystals. Typical features for a tunneling process like the approach to a constant low-temperature rate, a non-Arrhenius temp
โฆ LIBER โฆ
EPR-study of a photochemical hydrogen transfer reaction in phenazine doped fluorene crystals
โ Scribed by R. Furrer; J. Petersen; D. Stehlik
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 552 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0301-0104
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Tunneling in photochemical solid-state H
โ
M. Tietje; C. Von Borczyskowski; B. Prass; D. Stehlik
๐
Article
๐
1986
๐
Elsevier Science
๐
English
โ 777 KB
EPR and luminescence data of various pho
โ
C. von Borczyskowski; B. Prass; P. Steidl; D. Stehlik
๐
Article
๐
1984
๐
Elsevier Science
๐
English
โ 165 KB
Photochemically induced hydrogen elimina
โ
B. Prass; C. von Borczyskowski; D. Stehlik
๐
Article
๐
1987
๐
Elsevier Science
๐
English
โ 297 KB
The kinetics of the photochemical hydrog
โ
J.P. Colpa; D. Stehlik
๐
Article
๐
1982
๐
Elsevier Science
๐
English
โ 874 KB
Radical pair formation and decay by phot
โ
R. Furrer; F. Fujara; C. Lange; D. Stehlik; W. Vollmann
๐
Article
๐
1980
๐
Elsevier Science
๐
English
โ 802 KB
The method of ESR transient nutatlon has been used to kestipate the kinetics of formation and decay of a radical pair triplet state due to photochemical hydrogen transfer. The detaikd analysis of the observed transients restrains the possible reaction mechanisms.
Kinetics of photochemical hydrogen abstr
โ
Hans-Martin Vieth
๐
Article
๐
1983
๐
Elsevier Science
๐
English
โ 502 KB