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Pressure dependence of the low-temperature tunneling rate for the hydrogen transfer in acridine-doped fluorene crystals

✍ Scribed by I.Y. Chan; Chung M. Wong; D. Stehlik

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 783 KB
Volume: 219
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(94)87043-8

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✦ Synopsis

Pressure dependence of the tunneling rate for the hydrogen transfer photoreaction in acridine: fluorene was investigated at 1.4 K. Above 10 kbar, the rate rises exponentially with increasing pressure. These data constitute a measurement of tunneling rate from the vibrational ground state. Its physical implications are discussed.

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