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The Kinetics of the Iodine 2 -catalyzed Positional Isomerism of Butene-1. The Resonance Energy of the Allyl Radical

✍ Scribed by Benson, Sidney W.; Bose, A. N.; Nangia, P.

Book ID
127235837
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
236 KB
Volume
85
Category
Article
ISSN
0002-7863

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## Abstract The I~2~‐catalyzed isomerization of allyl chloride to __cis__‐ and __trans__‐ l‐chloro‐l‐propene was measured in a static system in the temperature range 225–329Β°C. Propylene was found as a side product, mainly at the lower temperatures. The rate constant for an abstraction of a hydroge