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Iodine-Catalyzed Isomerization of Olefins. III. Kinetics of the Geometrical Isomerization of Butene-2 and the Rate of Rotation About a Single Bond

โœ Scribed by Benson, Sidney W.; Egger, Kurt W.; Golden, David M.

Book ID
118144625
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
887 KB
Volume
87
Category
Article
ISSN
0002-7863

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Kinetics of the iodine atom catalyzed ga
Kinetics of the iodine atom catalyzed gas phase geometrical isomerization of diiodoethylene. Rotation about a single bond
โœ David M. Golden; Shozo Furuyama; Sidney W. Benson ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 381 KB

The spectrophotometric determination of the rate of iodine atom catalyzed geometrical isomerization of diiodoethylene in the gas phase from 502.8 to 609.1"K leads to a rate constant for the bimolecular reaction between I and trans-diiodoethylene of log kt-JM-l sec-l) = 8.85 & 0.12 -(1 1.01 f 0.30)/6