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Iodine and Nitric Oxide Catalyzed Isomerization of Olefins. V. Kinetics of the Geometrical Isomerization of 1,3-Pentadiene, a Check on the Rate of Rotation about Single Bonds, and the Allylic Resonance Energy 1a

✍ Scribed by Egger, Kurt W.; Benson, Sidney W.

Book ID: 126976032
Publisher: American Chemical Society
Year: 1965
Tongue: English
Weight: 656 KB
Volume: 87
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja01093a006

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The spectrophotometric determination of the rate of iodine atom catalyzed geometrical isomerization of diiodoethylene in the gas phase from 502.8 to 609.1"K leads to a rate constant for the bimolecular reaction between I and trans-diiodoethylene of log kt-JM-l sec-l) = 8.85 & 0.12 -(1 1.01 f 0.30)/6