Iodine and Nitric Oxide Catalyzed Isomerization of Olefins. VII. The Stabilization Energy in the Pentadienyl Radical and the Kinetics of the Positional Isomerization of 1,4-Pentadiene 1
โ Scribed by Egger, Kurt W.; Benson, Sidney W.
- Book ID
- 127335496
- Publisher
- American Chemical Society
- Year
- 1966
- Tongue
- English
- Weight
- 759 KB
- Volume
- 88
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
The gas phase, nitric oxide catalyzed positional isomerization of 3-methylene-l,5,5-trimethylcvclohexene (MTC) into 1,3,5,5-tetramethyl-1,3-cyclohexadiene (TECD) has been studied for temperatures ranging between 296' and 425'C. The major reaction was first order with respect to nitric oxide and to M
The kinetics of the nitric oxide catalyzed, homogeneous, gas-phase isomerizatioil of 1 ,trans-3,trans-5-heptatriene have been studied for temperatures ranging between 130ยฐC and 241ยฐC. The very clean reaction involves exclusive geometrical isomerization about the 5,6-x-bond. The observed rate constan