The kinetics of cationic polymerization of trioxan in the solid phase
โ Scribed by E.V. Prut; N.S. Yenikolopyan
- Book ID
- 118358114
- Publisher
- Elsevier Science
- Year
- 1967
- Weight
- 292 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0032-3950
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Cationic polymerizations of trioxane in 1,2-ethylene dichloride and benzene were heterogeneous and reversible. Phase separation accompanying with crystallization occurred during the polymerization. Three morphological changes were found in the course of the polymerization as were investigated by dil
In the cationic polymerization of trioxane initiated by BF, etheratc in cyclohexane solution, the rate of polymerization may be practically zero after a long period at 56 ยฐ. If the reaction mixture is then cooled at a controlled rate, it is possible to obtain further increments both in yield and in