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Cationic polymerization of trioxane in solid phase

โœ Scribed by Okamura, S. ;Kobayashi, E. ;Takeda, M. ;Tomikawa, K. ;Higashimura, T.


Book ID
105339773
Publisher
Wiley (John Wiley & Sons)
Year
2007
Weight
682 KB
Volume
4
Category
Article
ISSN
0449-2994

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Solid-state polymerization of trioxane
โœ Rao, H. ;Ballantine, D. S. ๐Ÿ“‚ Article ๐Ÿ“… 1965 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 514 KB
Termination processes in the cationic po
โœ F. Morelli; R. Tartarelli; G. Masetti ๐Ÿ“‚ Article ๐Ÿ“… 1968 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 151 KB

In the cationic polymerization of trioxane initiated by BF, etheratc in cyclohexane solution, the rate of polymerization may be practically zero after a long period at 56 ยฐ. If the reaction mixture is then cooled at a controlled rate, it is possible to obtain further increments both in yield and in