✍ Scribed by P.F. Aramendía; H.J. Schumacher
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📜 SIMILAR VOLUMES
The kinetics of the thermal reaction between SF, and CF,OF has been studied between 142°C and 185°C. The reaction was found to be homogeneous and the only products formed are equimolecular amounts of SF, and CF,O,CF, and smaller amounts of CF,OSF,. The reaction mechanism was not affected by the tot
## Photolysis of [Mo(CN) 8 ] 4Ϫ in the presence of diethylenetriamine (dien) leads to the complexation of ligand via hydrogen in the stoichiometry 2:1. The mechanism of the complexation was investigated by spectroscopy absorption and the rate constants and the quantum yield determined. Rate consta
The kinetics of the oxidation of S20:-by CIOz-have been studied in aqueous alkaline solution at 90°C using classical titrimetric methods to follow the course of the reaction. The reaction takes place according to the stoichiometry SzO: - + 2C10z-+ 20H-= 2S042-+ 2Cl-+ H 2 0 even in large SzO:excess.
The kinetics of the thermal reaction between CF,OF and C,F, have been investigated between 20 and 75°C. It is a homogeneous chain reaction of moderate length where the main product is a mixture of the two isomers l-C,F,OCF, (68%) and 2-C3F,0CF3 (32%). Equimolecular amounts of CF,OOCF, and CsF,, are