The kinetic isotope effect in the reaction of H 2 with OH
β Scribed by Ehhalt, D. H.; Davidson, J. A.; Cantrell, C. A.; Friedman, I.; Tyler, S.
- Book ID
- 119721205
- Publisher
- American Geophysical Union
- Year
- 1989
- Tongue
- English
- Weight
- 594 KB
- Volume
- 94
- Category
- Article
- ISSN
- 0148-0227
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract Recently, we have discovered the unusual inverse temperature dependence of the kinetic isotope effect (KIE) for the OH + __c__βC~6~H~12~/__c__βC~6~D~12~ reaction in water. Temperature increase causes a KIE increase; this is valid for both the Fenton system (I) and the HOONOο£ΏH~2~O system
## Abstract The kinetic isotope effect (KIE) for carbon and oxygen in the reaction CO + OH has been measured over a range of pressures of air and at 0.2 and 1.0 atm of oxygen, argon, and helium. The reaction was carried out with 21β86% conversion under static conditions, utilizing the photolysis of
The high-pressure bmiting rate constants of the reactlons between H or D atoms and three isotopic ethylenes have been measured in the temperature range 206-461 K. PractxaUy no isotope effects due to the differences between the ethylefies could be observed This result does not agree with the predicti