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Kinetic isotope effect in the reaction of oh radical with acetone-D6

✍ Scribed by Farkas, Edit ;Szilágyi,, István ;Dóbé, Sándor ;Bérces, Tibor ;Márta, Ferenc

Book ID: 111606098
Publisher: Springer
Year: 2003
Tongue: English
Weight: 115 KB
Volume: 80
Category: Article
ISSN: 0133-1736
DOI: 10.1023/b:reac.0000006145.52881.dc

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## Abstract The kinetic isotope effect (KIE) for carbon and oxygen in the reaction CO + OH has been measured over a range of pressures of air and at 0.2 and 1.0 atm of oxygen, argon, and helium. The reaction was carried out with 21–86% conversion under static conditions, utilizing the photolysis of