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Kinetic isotope effects in the reaction H + C2H4 → C2H5

✍ Scribed by Ko-Ichi Sugawara; Kiyoshi Okazaki; Shin Sato

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
416 KB
Volume
78
Category
Article
ISSN
0009-2614

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✦ Synopsis

The high-pressure bmiting rate constants of the reactlons between H or D atoms and three isotopic ethylenes have been measured in the temperature range 206-461 K. PractxaUy no isotope effects due to the differences between the ethylefies could be observed This result does not agree with the prediction recently made by the activated complex theory.

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