The kinetic effects of water and of cyclodextrins on Diels?Alder reactions. Host?guest chemistry. Part 18
✍ Scribed by Sangwan, Naresh K.; Schneider, Hans-J�rg
- Book ID
- 120742091
- Publisher
- Royal Society of Chemistry
- Year
- 1989
- Tongue
- English
- Weight
- 567 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1472-779X
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The hetero Diels‐Alder reaction of the enamino ketones 1b and 1c with ethyl vinyl ether (2) in dichloromethane to give the dihydropyrans 3b/4b and 3c/4c is studied at high pressure up to 5 kbar. The kinetics is measured by on‐line FT‐IR spectroscopy up to 3 kbar. The cycloadditions show
Hetero Diels-Alder reactions, intramolecular / High-pressure reactions / Diastereoselectivity / Pyrans / 1 -Oxa-l,3-butadiens / Isoxazolones The intramolecular hetero Diels-Alder reaction of the benzylidene-isoxazolone 3 giving the adducts 4 and 5 is studied in dichlormethane under high pressure up
## Abstract The hetero Diels‐Alder reactions of enamino ketones 1 and 2 with the vinyl ethers 3–5a are studied in dichloromethane solution under high pressures up to 5 kbar. The kinetics is measured by on‐line FT‐IR spectroscopy to 3 kbar. The cycloaddition reactions of enamino ketones 1 and 2 with