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The Isoparametricity Phenomenon in the Reactions of Benzoyl Halides and Benzyl Bromides with Anilines

✍ Scribed by Igor V. Shpan’ko

Book ID
111729336
Publisher
Royal Society of Chemistry
Year
1991
Tongue
English
Weight
263 KB
Volume
1
Category
Article
ISSN
0959-9436

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✍ Anatoly M. Egorov; Svetlana A. Matyukhova; Alexander V. Anisimov 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 163 KB

## Abstract The reaction of copper with benzyl bromides in hexamethylphosphoramide has been studied. The kinetic and thermodynamic parameters of the reaction have been obtained. Hammett plots of log (__k__/__k__^o^) vs the substituent constant σ gave good correlations (ρ = 0.15, __S__~ρ~ = 0.02, __