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The Isomerization by Base of Alkyl Allyl Sulfides to Alkyl Propenyl Sulfides. The Mechanism of the Reaction 1

✍ Scribed by Tarbell, D. S.; Lovett, William E.

Book ID: 121352662
Publisher: American Chemical Society
Year: 1956
Tongue: English
Weight: 865 KB
Volume: 78
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja01591a063

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Recently, the base-catalyeed isomarlcations ethers1 \*\* and l-to 2-olafI& bave baen reported of ally1 to propenyl to be hiShly selective in yialding the a-isomers. We wish to report on a similar isomariratioa of tert'kary ally1 ulnes which appears to be very much less selective under coadltions ess