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The Mechanism of the Alkyl Sulfide—Sulfinic Acid Reaction. The Direction of Cleavage of Unsymmetrical Sulfides 1a

✍ Scribed by Kice, John L.; Toth, Bruce R.; Hampton, David C.; Barbour, James F.

Book ID
121413483
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
638 KB
Volume
31
Category
Article
ISSN
0022-3263

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## Abstract A number of unsymmetrical acyl thioacyl sulfides [RC(S)S(O)CR'] have been prepared and characterized by the reaction of piperidinium or sodium dithiocarboxylates with acyl chlorides or by desulfurization reaction of acyl thioacyl disulfides with triphenylphosphine. They are deep blue oi