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The Isomeric 2-Pentenes 1

โœ Scribed by Lucas, Howard J.; Prater, Arthur N.


Book ID
126849009
Publisher
American Chemical Society
Year
1937
Tongue
English
Weight
535 KB
Volume
59
Category
Article
ISSN
0002-7863

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H,S accelerates the thermal isomerization of cis-2-pentene (P2c) to 1-pentene (P1) and trans-2-pentene (P2t) to around 800 K. This effect is interpreted on the basis of a free radical mechanism in which 2-pentenyl and thiyl radicals are the main chain carriers. P1 formation is essentially explained