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Skeletal isomerization of 1-pentene

✍ Scribed by Walendziewski, Jerzy ;Pniak, Barbara


Book ID
112684778
Publisher
Springer
Year
1996
Tongue
English
Weight
299 KB
Volume
58
Category
Article
ISSN
0133-1736

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H2S-promoted thermal isomerization of ci
✍ D. Perrin; C. Richard; R. Martin πŸ“‚ Article πŸ“… 1988 πŸ› John Wiley and Sons 🌐 English βš– 457 KB

H,S accelerates the thermal isomerization of cis-2-pentene (P2c) to 1-pentene (P1) and trans-2-pentene (P2t) to around 800 K. This effect is interpreted on the basis of a free radical mechanism in which 2-pentenyl and thiyl radicals are the main chain carriers. P1 formation is essentially explained