H2S-promoted thermal isomerization of ci
โ
D. Perrin; C. Richard; R. Martin
๐
Article
๐
1988
๐
John Wiley and Sons
๐
English
โ 457 KB
H,S accelerates the thermal isomerization of cis-2-pentene (P2c) to 1-pentene (P1) and trans-2-pentene (P2t) to around 800 K. This effect is interpreted on the basis of a free radical mechanism in which 2-pentenyl and thiyl radicals are the main chain carriers. P1 formation is essentially explained