The isolated CH chromophore in CD2FH and CD3H
โ Scribed by Kevin M. Dunn
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 469 KB
- Volume
- 139
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
The occurrence and magnitude of secondary kinetic isotope effects in the gas phase has been detcrmmcd for deuterium abstraction from the CD3 group in CD$ZH$l. CD$HDCI. and CD-&D&l by phorochemically generated \_eroundstaxe chlorine aloms. Over the temperature range lo-94ยฐC a discernible "inverse" ki
Product distributions for the reactions of CH$ and CDf with methanol, methanol-da, and ethanol studied in a tandemkm CpdOtrOTl resonance mass SpeCtrOmeter are reported. The major reaction pathways may 5c rationalized in terms of 3x1 intermediate species havving a pro&mated ether structure. The react
The ฮฝ 5 fundamental (C-C stretching) of CH 3 CD 3 shows a resolved torsional structure, caused by perturbations due mainly to the linear dependence of the torsional potential barrier on the normal coordinate Q 5 . We were able to analyze this structure and to assign vibration-rotation transition wav