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The Iron(III)-Catalyzed Oxidation of Ethanol by Hydrogen Peroxide: A Thermokinetic Oscillator

✍ Scribed by Zeyer, K.-P.; Mangold, M.; Obertopp, T.; Gilles, E. D.

Book ID
127313270
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
120 KB
Volume
103
Category
Article
ISSN
1089-5639

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Efficient solvent-free iron (III) cataly
Efficient solvent-free iron (III) catalyzed oxidation of alcohols by hydrogen peroxide
✍ Sandra E Martı́n; Analı́a Garrone πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 258 KB

Selective oxidation of secondary and benzylic alcohols was efficiently accomplished by H 2 O 2 under solvent-free condition catalyzed by FeBr 3 . Secondary alcohols are selectively oxidized even in the presence of primary ones. This method is high yielding, safe and operationally simple.