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The ionization energy of nitric oxide

✍ Scribed by Georg Reiser; Wieland Habenicht; Klaus Müller-Dethlefs; Edward W. Schlag

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
450 KB
Volume
152
Category
Article
ISSN
0009-2614

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✦ Synopsis

We report the discovery of high-lying, very-lung-lived Rydberg states in NO. With that we were able to determine the ionization potential of NO to be 74721.7 & 0.4 cm-'. The existence ofthese States explains a discrepancy between the values for the ionizatlon energy of NO from "zero kinetic energy photoelectron spectroscopy" and Rydbcrg f-series extrapolations. Now these values are in perfect agreement. Hence we propose a general method for the direct measurement of highly accurate ionization potentials.

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