✦ LIBER ✦

Investigation of aliphatic dienes by chemical ionization with nitric oxide

✍ Scribed by H. Budzikiewicz; St. Blech; B. Schneider

Publisher: John Wiley and Sons
Year: 1991
Tongue: English
Weight: 285 KB
Volume: 26
Category: Article
ISSN: 1076-5174
DOI: 10.1002/oms.1210261205

No coin nor oath required. For personal study only.

✦ Synopsis

Dedicated to Professor Dr G. Spiteller on the occasion of his 60th birthday It is shown that the position of the double bond close to the hydrocarbon end of an aliphatic diene functionalized at C(1) can readily be determined by chemical ionization with N O ' . Owing to the low abundance of the ions cbaracteristic for the position of the other double bond, its localization may be difficult. Measurement of the chemical ionization (nitric oxide as reagent gas) spectra of the corresponding epoxides or collision activation studies can help.

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