The infrared spectrum and barriers hindering internal rotation in H2S2, CF3SH, and CF3SD
β Scribed by R.L. Redington
- Publisher
- Elsevier Science
- Year
- 1962
- Tongue
- English
- Weight
- 498 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0022-2852
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π SIMILAR VOLUMES
Receised 7 February -969 Distortional effects on the barrier to L?p?nal rotation of ethane x-e investigated through ab tnttto calculations. yielding a theoretical barrier of 3.071 kcal/mole (experimental 2.928 kcal/mole). The com-Lwted barrier is 3.064 kcal/moIe ior borazane and 1.44 kcal/mole for m
The microwave spectra of sym-CHa DCHO and sym\_CHDaCHO have been measured. In the ground torsional state, the spectra correspond to localised conformers with only a small amount of sym-asym coupling. Apphcation of Watson's reduced haniltonia~ has enabled precise distortion constants free from intern