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Distortional effects on the ethane internal rotation barrier and rotation barriers in borazane and methylsilane

✍ Scribed by A. Veillard

Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
326 KB
Volume
3
Category
Article
ISSN
0009-2614

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✦ Synopsis

Receised 7 February -969 Distortional effects on the barrier to L?p?nal rotation of ethane x-e investigated through ab tnttto calculations. yielding a theoretical barrier of 3.071 kcal/mole (experimental 2.928 kcal/mole). The com-Lwted barrier is 3.064 kcal/moIe ior borazane and 1.44 kcal/mole for methylsilane (experimental 1.71 &al/mole).

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