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The influence of the magnetic field on the photosubstitution reaction of coordination complexes

โœ Scribed by G. Ferraudi; M. Pacheco

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
258 KB
Volume
112
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Photolyses of rhodium(III) complexes, Rh(NH3)sX3 (X = CI-and Br_), under intense m%netic fields, e.g. &,-it = 360 nm and H = 24 kG, have been investigated. The magnetic field quenches the photoaquation of the ammonia and enhances the photoaquation of the acid0 @and, X = Cl-or Br-, by 10% for H = 24 kG. The implication of two different precursors in the formation of the photoproducts is discussed_

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