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The Influence of Structural Changes in the Aglucons on the Enzymic Hydrolysis of Alkyl β-D-Glucosides1

✍ Scribed by Pigman, William Ward; Richtmyer, Nelson K.

Book ID
111919368
Publisher
American Chemical Society
Year
1942
Tongue
English
Weight
683 KB
Volume
64
Category
Article
ISSN
0002-7863

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Influence of the location of substituent
Influence of the location of substituents in substituted celluloses on solution hydrolysis of the d-glucosidic linkages
✍ Stanley P. Rowland; Phyllis S. Howley 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 526 KB

Sensitivity of the D-glucosidic linkages in cellulose to hydrolysis in homogeneous acidic media was found to be directly related to the location of a substituent in the o-glucoyranosyl unit. The 2-diethylaminoethyl (DEAE) substituent caused sensitivity toward hydrolysis to decrease in the order o-gl