The influence of coalescence on the morphology of the minor phase in melt-drawn polyamide-6/HDPE blends
✍ Scribed by R. González-Núnez; D. De Kee; B.D. Favis
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 623 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0032-3861
No coin nor oath required. For personal study only.
✦ Synopsis
The influence of coalescence on the final state of elongation of the dispersed phase in polyamide-6/HDPE blends was studied. The blends were prepared by ribbon extrusion and melt drawn at different draw ratios in order to obtain a high variation in the state of fibrillation of the minor phase. In order to separate out the relative role of single particle deformation and coalescence in determining the final morphology, coalescence was suppressed by two techniques. Firstly, coalescence was diminished to a small effect by studying the behaviour of the blend containing only 1 vol% polyamide-6 (PA-6). In the other case coalescence was suppressed in a blend containing 20 vol% PA-6 by adding an interfacial modifier. The results indicate that the form factors for 1% PA-6/HDPE and 20% PA-6/HDPE (compatibilized) are identical over a wide range of hot stretch ratios and the final state of elongation is dominated entirely by single particle deformation phenomena. The 20% PA-6/HDPE (uncompatibilized) system displays an added strong contribution of coalescence to the final morphology. The relative contribution of coalescence and single particle deformation in influencing the final morphology in this latter system can be inferred quantitatively from these results.
📜 SIMILAR VOLUMES
## Abstract A ternary blend of the PA6 matrix with a finely dispersed rigid polymer and elastomer is a system with well‐balanced mechanical properties. Its micromechanical behavior, especially that of the elastomer phase, apparently differs from corresponding binary mixtures. This study shows the i
With the purpose of improving the mechanical properties of the polyamides, the possibility of combining polyamides with elastomers has been used. The low compatibility of the resulting blends leads to deficient mechanical properties, and therefore, it is necessary to add the compatibilizer to the mi
The compatibilizing effect of polypropylene (PP) grafted with hyperbranched polymers (PP-HBP) has been investigated in PP/polyamide-6 (PA-6) blends. Because of its high reactivity and diffusitivity, PP-HBP has been shown to be a more effective compatibilizer in decreasing the interfacial tension tha
Phase separation behaviors of the blends that consist of high-density polyethylene (HDPE) and LP was investigated by means of thermal analysis. The miscibility of the two components was evaluated in terms of the Flory-Huggins interaction parameter, determined from the Hoffman-Weeks plot, gave a valu
## Abstract Antiparallel polyamides containing 1__H__‐pyrrole, 1__H__‐imidazole, and 3‐hydroxy‐1__H__‐pyrrole amino acids display a preference for minor‐groove binding oriented NC with respect to the 5′‐3′ direction of the DNA helix. We find that replacement of a central Py/Py pair with a __β__/__