Abstract
A ternary blend of the PA6 matrix with a finely dispersed rigid polymer and elastomer is a system with well‐balanced mechanical properties. Its micromechanical behavior, especially that of the elastomer phase, apparently differs from corresponding binary mixtures. This study shows the influence of the elastomer type, modulus, and reactivity on the behavior of ternary blends in comparison with analogous binary PA6/elastomer combinations. The presence of rigid reactive poly(styrene‐co‐maleic anhydride) (SMA) enhanced the properties of all the systems studied. For nonreactive elastomers, the dominant effect was refinement of their size due to enhanced viscosity, whereas for functionalized low‐modulus elastomers, the very good balance of properties was due to synergistic influences of both finely dispersed phases. Of interest is the enhanced toughness of ternary blends also for more rigid elastomers having a low toughening efficiency in binary blends. An appropriate addition of rigid SMA together with an elastomer enhances the energy absorption of the matrix, probably without cavitation of very small elastomer particles. Of importance also is the simultaneous strain‐hardening effect of deformed rigid particles. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 3647–3651, 2003