Swmnurz~: EPR evidence supporting a single electron transfer mechanism in the reduction of secondary and tertiary alcohols to hydrocarbons with LiAlH4 is presented.
The importance of entropy in stereoselection. Reduction of tert-butylcyclohexanone by lithium aluminum hydride
β Scribed by Robert E. Rosenberg; Jonathan S. Vilardo
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 206 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Treatment of 2,3:4,5-di-g-isopropylidene-k-arabinose diphenyl dithioacetal (la) with sodium methylsulfinyl carbanion in DMSO has previously been shown2 to produce ga via extraction of the acidic C-l hydrogen and concomitant elimination of acetone. Workup of the reaction with water gave 2-deoxy-4,5-Q
Lithium aluminum hydride, in the presence of a small amount of silica gel, has been found to be a versatile and highly selective reagent for reduction of various ketoesters to the corresponding hydroxyesters in fair yields. Recently we reported a series of new synthetic reactions l-7) with the use