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Evidence for single electron transfer in the reduction of alcoholswith lithium aluminum hydride

โœ Scribed by E.C. Ashby; A.B. Goel

Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
129 KB
Volume
22
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Swmnurz~: EPR evidence supporting a single electron transfer mechanism in the reduction of secondary and tertiary alcohols to hydrocarbons with LiAlH4 is presented.

๐Ÿ“œ SIMILAR VOLUMES

Evidence for a single electron transfer
Evidence for a single electron transfer mechanism in the reduction of benzophenone with lithium alkoxides
โœ E.C. Ashby; J.N. Argyropoulos ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 273 KB

The reduction of benzophenone by lithium alkoxides gives rise to benzophenone ketyl which disappears in a first-order fashion and whose first-order rate constant is approximately equal to the pseudo-first-order rate constant for the formation of the product, benzhydrol.

Reduction of aryl bromides with lithium
Reduction of aryl bromides with lithium aluminum hydride: Evidence for a radical mechanism
โœ Sung-Kee Chung; Fu-fan Chung ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 214 KB

Reduction of c-bromophenyl ally1 ether with LiAlH4 yields phenyl ally1 ether 3-methyl-2,3\_dihydrobenzofuran, thus suggesting the involvement of radical intermediates in reduction. and the Metal hydrides' are generally considered to react as nucleophilic hydride species. Reduction of the carbonyl gr