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The Hydrolysis of Nitriles with Acids

✍ Scribed by Krieble, Vernon K.; Noll, Clarence I.


Book ID
125838320
Publisher
American Chemical Society
Year
1939
Tongue
English
Weight
372 KB
Volume
61
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES


Hydrolysis in the absence of bulk water
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The reaction of nitriles with tetrafluorophthalic or tetrachlorophthalic acid gives carboxylic acids in good yield. The reaction is chemoselective in that the nitrile functionality can be hydrolyzed in the presence of ester groups.

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The reaction of nitriles with O,O-dialky
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Nitrlles react with dlslkyldithlophosphorlc acids za-c to give a mixture of corresponding thiosmldes and O,Odlalkyl-N-thioaceyl-phosphoroamldothloates ?a-e. The structure of compounds 1 are elucidated chemically and from electronic spectra. The yield of thloamides are improved from the reactlon of n