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The reaction of nitriles with O,O-dialkyldithiophosphoric acids

✍ Scribed by N.M. Yousif

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 259 KB
Volume: 45
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)89095-5

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✦ Synopsis

Nitrlles react with dlslkyldithlophosphorlc acids za-c to give a mixture of corresponding thiosmldes and O,Odlalkyl-N-thioaceyl-phosphoroamldothloates ?a-e. The structure of compounds 1 are elucidated chemically and from electronic spectra. The yield of thloamides are improved from the reactlon of nItriles with compound 2b in presence of water. Mechsnlstlc consideration on the formatlon of the products sre dlscussed.

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