Spiroheterocycles from reaction of nitrile oxides with heterocyclic o-quinodimethanes
β Scribed by Sophia Mitkidou; Julia Stephanidou-Stephanatou; Aristides Terzis; Demetrios Mentzafos
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- French
- Weight
- 639 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0040-4020
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β¦ Synopsis
1.5418), with scan width 1.6O (20) plus al-a2 divergence, 28max=130Β°. Out of 5277 measured reflections 4945 were considered observed with IFo@~u((FoI). Lorentz, polarization and absorption corrections were applied. The structure was solved by direct methods and refined by full matrix least squares using SHELX7614 with all non-H atoms refined anisotropically. The H-atoms were located from difference Fourier maps. Final R&=0.0497/0.0726 for observed data using a weighting scheme w=l/(02(Fo)t0.00007F02).
π SIMILAR VOLUMES
## Abstract Critical to this reaction is the development of a biphasic system for baseβinduced dehydrohalogenation of hydroximoyl chlorides, to give nitrile oxides, in the presence of a baseβsensitive dipolarophile.
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