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The hydrogen atom channel in the photodissociation of HNCO

โœ Scribed by Whikun Yi; Richard Bersohn

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
362 KB
Volume
206
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

In the photodissociation of HNCO at 193.3 and 212.6 nm the main channel is NH(a 'A) t CO but the channel HtNCO has also been observed with a yield of 0.050 f 0.006 at 193.3 MI and 0.13 + 0.0 1 at 212.6 nm. Tbe average kinetic energy of the H atoms at 193.3 and 212.6 nm is 10.7 + 1.5 and 11.4? 0.6 kcal/mol respectively. Results are compared with similar data recently repotted for HN,.

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