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The high-spin/low-spin equilibrium in cytochrome P-450 — A new method for determination of the high-spin content

✍ Scribed by Christiane Jung; Otto Ristau; Horst Rein


Book ID
113268433
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
437 KB
Volume
1076
Category
Article
ISSN
0167-4838

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The Fe"(TRIM),(PhCO,) (ClO,) spin crossover complex (TRIM = 4'-(4-methylimidazole )-2'-(2"-methylimidazole) imidazole, PhCOr = C6H5C02) has been synthesized and investigated by Miissbauer spectroscopy and magnetic susceptibility measurements as a function of temperature. The spin conversion is gradu