A new aspect of size effect on the high-spin(5T2)-low-spin(1A1) transition in supported ferrous complexes
β Scribed by Y. C. Jean; H. H. Wei
- Book ID
- 112682258
- Publisher
- Springer
- Year
- 1986
- Tongue
- English
- Weight
- 219 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0304-3843
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Based on measurements of differential scanning calorimetry, the first-order character of the spin-state transition in Fe(bt),(NCS), is established (bt = 2,2'-bi-2-thiazoline). The transition arises at T, ' =180.9 K and T,l =171.2 K, and is characterized by AH = 9.55 kO.7 kJ mol-' and AS = 54.5 \*4 J
Employmg snmplcs cnrichcd to >90% in 57Fc, hlbssbducr cffcct studlcs dcmonstratc that high-spin (%2) := low-spm ('A1) transitions arc responsible for the peculiar tempcraturc dcpendcncc of the mdgnctlsm in ccrtam [fc(paptH)z ] X2 l nH20 complcxcs where paptH = 2-(2-pyridyhho) -4-(2-pyrldyl)thiai!olc