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The Gibbs-Duhem equation in membrane transport

✍ Scribed by B. Tomicki

Book ID: 104685031
Publisher: Springer
Year: 1989
Tongue: English
Weight: 541 KB
Volume: 17
Category: Article
ISSN: 1432-1017
DOI: 10.1007/bf00254767

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Various ways of building quasi-Newton matrix approximations that satisfy the special form of the Gibbs-Duhem equation are studied. Partition symmetry, the separability of the functions In y and In 4, and the method of iterated projections are used in order t o develop thermodynamically consistent ma

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✍ H.C. Van Ness 📂 Article 📅 1959 🏛 Elsevier Science 🌐 English ⚖ 308 KB

The exact forms of the Gibbs-Duhem equation in terms of fugacities and activity coefficients, applicable to any multicomponent phase, are developed in a straightforward manner. Reduction to restricted equations valid for constant temperature, constant pressure, or constant composition becomes a simp