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Deriving the Gibbs-Duhem equation

✍ Scribed by Rogers, D. W.

Book ID: 120509976
Publisher: American Chemical Society
Year: 1962
Tongue: English
Weight: 676 KB
Volume: 39
Category: Article
ISSN: 0021-9584
DOI: 10.1021/ed039p527

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📜 SIMILAR VOLUMES

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The exact forms of the Gibbs-Duhem equation in terms of fugacities and activity coefficients, applicable to any multicomponent phase, are developed in a straightforward manner. Reduction to restricted equations valid for constant temperature, constant pressure, or constant composition becomes a simp

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Various ways of building quasi-Newton matrix approximations that satisfy the special form of the Gibbs-Duhem equation are studied. Partition symmetry, the separability of the functions In y and In 4, and the method of iterated projections are used in order t o develop thermodynamically consistent ma