Extensivity and the Gibbs-Duhem equation
โ Scribed by J. Dunning-Davies
- Book ID
- 107986558
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 151 KB
- Volume
- 97
- Category
- Article
- ISSN
- 0375-9601
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The exact forms of the Gibbs-Duhem equation in terms of fugacities and activity coefficients, applicable to any multicomponent phase, are developed in a straightforward manner. Reduction to restricted equations valid for constant temperature, constant pressure, or constant composition becomes a simp
Various ways of building quasi-Newton matrix approximations that satisfy the special form of the Gibbs-Duhem equation are studied. Partition symmetry, the separability of the functions In y and In 4, and the method of iterated projections are used in order t o develop thermodynamically consistent ma