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The gas phase thermochemistry of the reaction: C2F5Br + I2 = C2F5I + IBr

โœ Scribed by Gary S. Buckley; W.G.F. Ford; Alan S. Rodgers

Book ID
107858450
Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
440 KB
Volume
49
Category
Article
ISSN
0040-6031

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The reactions (1) ( 2 ) have been studied competitively over the range of 2%182'C by photolysis of mixtures of C12 + C2F5I + CH4. We obtain log k l / k 2 = (0.96 f 0.06) + (1210 f 440)/0 where 0 = 2.303RT J/mol. The use of published data on reaction (2) leads to log (kl(cms/mol sec) = (13.96 f 0.2)