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The determination of the arrhenius parameters for the reaction Cl + C2F5I → ICl + C2F5 using a competitive method

✍ Scribed by Samuel I. Ahonkhai; Eric Whittle

Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
240 KB
Volume
13
Category
Article
ISSN
0538-8066

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✦ Synopsis

The reactions (1) ( 2 ) have been studied competitively over the range of 2%182'C by photolysis of mixtures of C12 + C2F5I + CH4. We obtain log k l / k 2 = (0.96 f 0.06) + (1210 f 440)/0 where 0 = 2.303RT J/mol. The use of published data on reaction (2) leads to log (kl(cms/mol sec) = (13.96 f 0.2) -(11,500 f 2000)/0

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