The free radical chemistry of acyl tellurides: Mechanistic studies and synthetic applications
β Scribed by Chen Chen; David Crich
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- French
- Weight
- 241 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
A pulse radiolysis system was used to study the kinetics of the reaction of FC(0)Oz radicals with NOz. By monitoring the rate of the decay of NO2 using its absorption at 400 nm the reaction rate constant was determined to be (5.5 ? 0.6) X 10-l' cm3 molecule-' 5-l a t 296 K and 500-1000 mbar pressure
The photochemically initiated reactions and the atmospherically initiated reactions of alkyl aryl tellurides with electron-deficient heteroaromatic bases in the presence of N-acetoxy-2-thiopyridone and triethylborane, respectively, have been investigated. These reactions were applied to the preparat